TitleMacromolecular metal carboxylates and their nanocomposites
Author(s)A.D. Pomogailo;G.I. Dzhardimalieva;V.N. Kestelman
PublicationHeidelberg, Springer, 2010.
Description1 online resource (x, 305 p.) : ill. (some col.)
Contents NoteCover13; -- Macromolecular Metal Carboxylates and Their Nanocomposites -- Preface13; -- Contents13; -- Chapter 1 Introduction -- References -- Chapter 2 Monomeric and Polymeric Carboxylic Acids -- 2.1 Mono- and Polybasic Unsaturated Carboxylic Acids: Characteristic and Polymerization -- 2.1.1 Monobasic Carboxylic Acids with One Double Bond -- 2.1.2 Unsaturated Dicarboxylic (Dibasic) Acids -- 2.1.3 Unsaturated Carboxylic Acids with Triple Bond (Acetylenic Acids) -- 2.2 Peculiarity of Polymerization of Unsaturated Carboxylic Acids and their Polymers Structure -- 2.3 Stereoregular Polyacids -- 2.4 Cross-Linked Polyacids -- 2.5 Graft- and Block-Copolymers with Carboxyl Fragments -- 2.6 Natural Polyacids -- 2.6.1 Polysaccharides -- 2.6.2 Humic Acids -- References -- Chapter 3 Synthesis of Unsaturated Carboxylic Acid Salts -- 3.1 Reaction of Unsaturated Carboxylic Acids with Metal Hydroxides, Oxides, and Carbonates -- 3.2 Reactions of Acetates and Other Salts with Unsaturated Carboxylic Acids -- 3.3 Ligand Exchange Reactions -- 3.3.1 With Metal Halides -- 3.3.2 With Metal Alkoxides -- 3.3.3 Other Exchange Reactions -- 3.3.4 Synthesis of Bimetallic Compounds -- 3.4 Sol8211;Gel Reactions -- 3.5 Other Reactions -- 3.6 Synthesis of Cluster Containing Unsaturated Carboxylates -- References -- Chapter 4 Spectral Characteristics and Molecular Structureof Unsaturated Carboxylic Acid Salts -- 4.1 Metal (Meth)acrylates -- 4.1.1 IR Spectroscopy -- 4.1.2 Magnetic Properties -- 4.1.3 Electron Spectroscopy -- 4.1.4 Molecular Structure -- 4.2 Metal Dicarboxylates -- 4.2.1 Monomeric Salts -- 4.2.2 Coordination Polymers -- 4.2.3 Ferromagnetic Properties of Metal Dicarboxylates -- 4.3 -Complexes of Metal Carboxylates -- 4.4 Unsaturated -Oxo Multinuclear Metal Carboxylates -- 4.4.1 IR-Spectroscopy -- 4.4.2 Mass-Spectrometry -- 4.4.3 Molecular Structure -- 4.5 Cluster-Containing Unsaturated Carboxylates -- 4.6 Metal Carboxylates with Unsaturated Ligands of Acetylene Type -- References -- Chapter 5 Polymerization and Copolymerization of Salts of Unsaturated Carboxylic Acids -- 5.1 Types of Initiation -- 5.2 Kinetic and Stereochemical Effects -- 5.2.1 Radical Polymerization of Alkali and Alkaline Earth Metal Salts of Unsaturated Carboxylic Acids -- 5.2.2 Radical Polymerization of TransitionMetal (Meth)acrylates -- 5.2.3 Regulation of Stereochemistry of Radical Polymerization of Metal Carboxylates -- 5.3 Solid Phase Polymerization of Unsaturated Metal Carboxylates -- 5.3.1 Thermal Polymerization of Unsaturated Metal Carboxylates -- 5.3.2 Solid State UV and Radiation Initiated Polymerization -- 5.3.3 Reactivity of Unsaturated Metal Carboxylatesin Solid Phase -- 5.4 Copolymerization and Terpolymerization -- 5.4.1 The Main Principles of Copolymerizationof Alkali and Alkaline Earth Metal Salts -- 5.4.2 Reactivity of Tin-Containing Carboxylates -- 5.4.3 Copolymerization of Transition Metal Salts -- 5.4.4 Kinetic Features -- 5.4.5 Terpolymerization -- References -- Chapter 6 Polymer-Analog Transformations in Reactionsof Synthesis of Metal Macrocarboxylates -- 6.1 Complexation of Metal Ions with Macromolecular Ligands -- 6.2 Metal Ion Binding by Polyacids -- 6.3 Metal Ion Binding by Stereoregular Polyacids -- 6.4 Peculiarities of MXn Binding by Cross-Linked Polyacids -- 6.5 Formation of Macrocomplexes with Grafted Polycarboxylic Fragments -- 6.6 Bimetallic Polycomplexes -- T$298
NotesIncludes bibliographical references and index
Keyword(s)1. Carboxylate 2. CHEMICAL ENGINEERING 3. EBOOK 4. EBOOK - SPRINGER 5. ENGINEERING 6. Macromolecules 7. Metallic soaps 8. Metallorganische Polymere 9. Nanocomposites (Materials) 10. TECHNOLOGY & ENGINEERING
Item TypeeBook
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