TitleFerroelectric Domain Walls : Statics, Dynamics, and Functionalities Revealed by Atomic Force Microscopy
Author(s)Guyonnet, Jill
PublicationCham, Springer International Publishing, 2014.
DescriptionXV, 159 p. 96 illus., 17 illus. in color : online resource
Abstract NoteUsing the nanometric resolution of atomic force microscopy techniques, this work explores the rich fundamental physics and novel functionalities of domain walls in ferroelectric materials, the nanoscale interfaces separating regions of differently oriented spontaneous polarization. Due to the local symmetry-breaking caused by the change in polarization, domain walls are found to possess an unexpected lateral piezoelectric response, even when this is symmetry-forbidden in the parent material. This has interesting potential applications in electromechanical devices based on ferroelectric domain patterning. Moreover, electrical conduction is shown to arise at domain walls in otherwise insulating lead zirconate titanate, the first such observation outside of multiferroic bismuth ferrite, due to the tendency of the walls to localize defects. The role of defects is then explored in the theoretical framework of disordered elastic interfaces possessing a characteristic roughness scaling and complex dynamic response. It is shown that the heterogeneous disorder landscape in ferroelectric thin films leads to a breakdown of the usual self-affine roughness, possibly related to strong pinning at individual defects. Finally, the roles of varying environmental conditions and defect densities in domain switching are explored, and shown to be adequately modelled as a competition between screening effects and pinning
ISBN,Price9783319057507
Keyword(s)1. EBOOK 2. EBOOK - SPRINGER 3. Electronic materials 4. Interfaces (Physical sciences) 5. MICROSCOPY 6. Nanoscale science 7. Nanoscale Science and Technology 8. NANOSCIENCE 9. Nanostructures 10. NANOTECHNOLOGY 11. Optical and Electronic Materials 12. OPTICAL MATERIALS 13. SPECTROSCOPY 14. Spectroscopy and Microscopy 15. Surface and Interface Science, Thin Films 16. Surfaces (Physics) 17. THIN FILMS
Item TypeeBook
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