TitleElectronic Structure of Metal Phthalocyanines on Ag(100)
Author(s)Krull, Cornelius
PublicationCham, Springer International Publishing, 2014.
DescriptionXVII, 146 p. 81 illus., 54 illus. in color : online resource
Abstract NoteThe application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip
ISBN,Price9783319026602
Keyword(s)1. Atomic, Molecular, Optical and Plasma Physics 2. ATOMS 3. EBOOK 4. EBOOK - SPRINGER 5. Electronic materials 6. Interfaces (Physical sciences) 7. MICROSCOPY 8. Optical and Electronic Materials 9. OPTICAL MATERIALS 10. Organometallic Chemistry 11. Organometallic chemistry?? 12. PHYSICS 13. SPECTROSCOPY 14. Spectroscopy and Microscopy 15. Surface and Interface Science, Thin Films 16. Surfaces (Physics) 17. THIN FILMS
Item TypeeBook
Multi-Media Links
Please Click here for eBook
Circulation Data
Accession#  Call#StatusIssued ToReturn Due On Physical Location
I08366     On Shelf