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 #  AuthorTitleAccn#YearItem Type Claims
1 Aresta, M Carbon Dioxide as a Source of Carbon I04205 1987 eBook  
2 Aresta, M Enzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization I03858 1990 eBook  
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1.    
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TitleCarbon Dioxide as a Source of Carbon : Biochemical and Chemical Uses
Author(s)Aresta, M;Forti, G
PublicationDordrecht, Springer Netherlands, 1987.
DescriptionXI, 441 p : online resource
ISBN,Price9789400939233
Keyword(s)1. BIOCHEMISTRY 2. Biochemistry, general 3. EBOOK 4. EBOOK - SPRINGER 5. ORGANIC CHEMISTRY 6. Plant physiology
Item TypeeBook
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Accession#  Call#StatusIssued ToReturn Due On Physical Location
I04205     On Shelf    

2.    
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TitleEnzymatic and Model Carboxylation and Reduction Reactions for Carbon Dioxide Utilization
Author(s)Aresta, M;Schloss, J.V
PublicationDordrecht, Springer Netherlands, 1990.
Description452 p : online resource
Abstract NoteThe activation of carbon dioxide by transition metal complexes has been extensively studied. both experimentally and theoretically. 1 Central reactions in this chemistry are the insertion of C02 into M-X bonds. where X = H. C. 0. and N. (eq. 1-4). We are presently investigating the mechanistic aspects of these reaction processes and will herein deSCribe our current level of understanding. Comparisons of the pathway of the carbon-carbon bond fonning process in transition metal chemistry with the well known analogous chemistry involving organolithium reagents will be presented. Furthermore. the role of these reaction types in both homogeneous and heterogenous catalytic processes leading to useful chemicals will be elaborated. _OM> (1) lMt-H + ~ lMlopi _OM> (2) [Mt-R + C0. 2 [M]0. 2CR _OM> (3) [Mt-OR+ ~ [M]0. 2COR _OM> (4) [Mt-NR2 + C0. 2 [M]~CNR2 Insertion of C02 into the Metal-Hydride Bond. The reaction of anionic group 6 (Cr. Mo. W) transition metal hydrides with carbon dioxide to afford metalloformates occurs readlly at ambient temperature and 2 reduced pressures of carbon dioxide. This insertion process is referred to the normal pathway (Scheme 1). There are no documented cases of C02 insertion into the metal hydride bond to provide the alternative. metallocarboxylic acid. isomer (referred in Scheme 1 as abnormal). 3 Recent theoretical studies ascribe this preference to an unfavorable electrostatic interaction and poorer orbital overlap in the latter pro?? 4 cess. Nevertheless
ISBN,Price9789400906631
Keyword(s)1. BIOCHEMISTRY 2. Biochemistry, general 3. EBOOK 4. EBOOK - SPRINGER 5. INORGANIC CHEMISTRY 6. ORGANIC CHEMISTRY 7. Plant physiology
Item TypeeBook
Multi-Media Links
Please Click here for eBook
Circulation Data
Accession#  Call#StatusIssued ToReturn Due On Physical Location
I03858     On Shelf    

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